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Updated: Jun 21, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

移行状態の電荷移転は,電愛性,両愛性,および核愛性炭素-水素結合の活性化を明らかにします

Daniel H Ess1, Robert J Nielsen, William A Goddard

  • 1Materials and Process Simulation Center, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.daniel@scripps.edu

Journal of the American Chemical Society
|August 6, 2009
PubMed
まとめ

C-H活性化移行状態は,金属の中心と結合に依存して,電離性から核愛性への電荷伝送 (CT) 連続体を示します. この発見は,新しい活性化反応と核愛性活性化複合体の設計に影響を与えます.

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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)06:34

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