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Updated: Jun 21, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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高酸化状態のロジウムとイリジウム・ビス・シリル・ダイヒドリドの複合体は,ケラート性ピリジル・ピロリド・リガンドによって支えられています

Jennifer L McBee1, Jose Escalada, T Don Tilley

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|August 18, 2009
PubMed
まとめ

新しいロジウムとイリジウムの複合体は,3,5-ディフェニル-2-(2-ピリジル) ピロリド (PyPyr) リガンドを使用して合成されました. これらの複合体は,新しいRh (V) とIr (V) ビス (シリル) ディヒドリドを形成し,機械学的研究により,シラン交換経路が明らかになりました.

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