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Updated: Jun 20, 2026

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
07:28

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

パラジアム・フォスフィン・スルフォナート複合体によって触媒化された線形ポリエチレン鎖の形成に関する機械学的研究:実験と理論的研究

Shusuke Noda1, Akifumi Nakamura, Takuya Kochi

  • 1Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-Ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|September 15, 2009
PubMed
まとめ

この研究では,パラジアム・フォスフィン・スルフォナート複合体が,高度に線形ポリエチレンを生成することを示しています. ユニークな硫酸塩リガンドは,望ましくないβ-水素除去を抑制しながら鎖の成長を促進し,高分子量ポリマー形成を可能にします.

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