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Updated: Jun 20, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
08:43

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives

Published on: January 19, 2016

ハフノセンの二酸化窒素複合体へのメチルトリフラートの添加:段階的なn(2) メチル化と,ハフノセンの水素酸塩化合物への変換

Donald J Knobloch1, David Benito-Garagorri, Wesley H Bernskoetter

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, 14853, USA.

Journal of the American Chemical Society
|September 30, 2009
PubMed
まとめ

二酸化窒素リガンドを含むハフノセンの複合体は,メチルトリフラートと反応してメチルディアゼニド化合物を形成する. さらに反応すると,希少なヒドラゾナト複合体が生み出され,ダイナトロゲン機能化の新たな経路が示される.

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