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Updated: Jun 20, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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初等デウテリウム同位体に対する構造反応性効果は,環置換アルファメトキシチルネスのプロトネーションに対する効果である

Wing-Yin Tsang1, John P Richard

  • 1Department of Chemistry, University of Buffalo, SUNY, Buffalo, New York 14260-3000, USA.

Journal of the American Chemical Society
|October 1, 2009
PubMed
まとめ

この研究では,アルファ-メトキシスティレンのプロトネーションにおける一次運動同位体効果 (PIEs) を調査した. 最大のPIEは0の反応推進力の近くで観察され,これは水素移転の対称的な移行状態を示唆しています.

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