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Updated: Jun 19, 2026

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
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低触媒負荷のエナミン触媒 - - 運動研究による高効率

Markus Wiesner1, Grégory Upert, Gaetano Angelici

  • 1Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland.

Journal of the American Chemical Society
|October 2, 2009
PubMed
まとめ

研究者らは,ペプチド触媒によるエナミン反応における,速度を制限する重要なステップを特定した. この発見により,結合添加反応の触媒負荷が著しく低下し,低分子量触媒で前例のない効率を達成することが可能になった.

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