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Updated: Jun 19, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

グループ4のメタルロケーン複合体は,ディジレン,ディゲルメン,シラゲルメンで構成される

Michaela Zirngast1, Michaela Flock, Judith Baumgartner

  • 1Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010 Graz, Austria.

Journal of the American Chemical Society
|October 6, 2009
PubMed
まとめ

研究者らは,テトラトリス ((trimethylsilyl)) ディジレン,ディゲルメン,シラゲルメンリガンドを含む新種のメタルロゼン複合体を合成した. いくつかの複合体は,トリメチルフォスファンのアダクトを分離するために必要であり,ディスタニンの反応は,ユニークな四つ組のリングを生成しました.

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The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable, the...
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In a Diels–Alder reaction, the diene is usually an electron-rich system and acts as a nucleophile, whereas the dienophile is electron-deficient and functions as an electrophile. Much like the diene, the nature of the dienophile significantly impacts the outcome of the reaction.
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