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Updated: Jun 19, 2026

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
09:45

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors

Published on: April 27, 2017

柔軟なリンク器を持つビス・グアニディノ化合物の超基本性:理論的および実験的研究

Martyn P Coles1, Pedro J Aragón-Sáez, Sarah H Oakley

  • 1Department of Chemistry, University of Sussex, Falmer, Brighton BN1 9QJ, UK. m.p.coles@sussex.ac.uk

Journal of the American Chemical Society
|October 31, 2009
PubMed
まとめ

この研究では,ビス-グアニジノ化合物H(2) C{hpp}(2) がスーパーベースとして作用し,窒素原子間の無障壁の陽子転送を示すことが明らかになりました. 顕微鏡および結晶学的データは,分子内水素結合とダイナミックな陽子のシャットリングを確認し,例外的な基本性をもたらしました.

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