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Updated: Jun 18, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
07:30

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

結合ニトリルラジカル複合体の反応性の調整モード制御:低温でエンドオンニトリル-Mo(III) ラジカルを遮断する

Meaghan E Germain1, Manuel Temprado, Annie Castonguay

  • 1Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts 02155, USA.

Journal of the American Chemical Society
|November 19, 2009
PubMed
まとめ

この研究は,金属-ニトリル複合体の反応性を調査し,リガンド結合ハプティシティが反応経路と速度にどのように影響するかを明らかにしています. これらのダイナミクスを理解することは,新しい触媒プロセスを設計する上で極めて重要です.

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