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Updated: Jun 17, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

ヘック反応における無結合性,アニオン性,アリルパラジウムハリドの中間物質である

Brad P Carrow1, John F Hartwig

  • 1Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|December 18, 2009
PubMed
まとめ

研究者らは,新しいアニオンアリルパラジウム複合体を分離した. これらの複合体は,ヘック-ミゾロキ反応の高度な反応性の中間物質であり,中性同類と比較してオレフィン挿入を著しく加速します.

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