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Updated: Jun 17, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

非共性ホスト・ゲスト相互作用に対する同位体効果の高精度測定

Jeffrey S Mugridge1, Robert G Bergman, Kenneth N Raymond

  • 1Department of Chemistry, University of California, Berkeley, and Chemical Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-1460, USA.

Journal of the American Chemical Society
|January 7, 2010
PubMed
まとめ

この研究では,超分子宿主と結合するゲスト分子の小さな均衡同位体効果を正確に測定しました. デュテレーションの位置は結合強度に影響を与え,ホスト-ゲストの相互作用の微妙な違いを明らかにしました.

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