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Updated: Jun 17, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

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高度にエナチオセレクティブの銅で触媒化されたアルファ-ディアゾスルフォンの分子内C-H挿入反応は,アルファ-ディアゾスルフォンの

Christopher J Flynn1, Curtis J Elcoate, Simon E Lawrence

  • 1Department of Chemistry, Analytical and Biological Chemistry Research Facility, University College Cork, Cork, Ireland.

Journal of the American Chemical Society
|January 7, 2010
PubMed
まとめ

銅触媒は,アルファ-ディアゾスルフォンの効率的なC-H挿入を可能にし,チオピランとスルフォランを生成します. この方法は優れたエナチオコントロールを達成し,チオピラン合成のエナチオメリック過剰 (ee) が最大98%に達します.

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