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Updated: Jun 16, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

パラジアム触媒によるクロスカップリング反応におけるリガンド制御の地域選択性

Franziska Schoenebeck1, K N Houk

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

Journal of the American Chemical Society
|February 4, 2010
PubMed
まとめ

計算による研究では,パラジウム触媒によるクロスカップリングにおける地域選択性が明らかになった. Palladium-HOMO ArO-LUMOの相互作用がC-Oの挿入を制御し,C-Clの挿入はC-Clのより低い移行状態の歪曲エネルギーに依存する.

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