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Updated: Jun 15, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Published on: June 24, 2022

均質なCO水素化:二水素の活性化には,プラチナ複合体の代わりに,挫折したルイス対が含まれる

Alexander J M Miller1, Jay A Labinger, John E Bercaw

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|February 25, 2010
PubMed
まとめ

研究者は,挫折したルイスペア (FLP) を使用して,CO削減のための金属フリー条件を発見しました. このフォスファゼン基とボラン系は,二水素によって活性化され,水素移転と炭素-炭素結合形成を可能にします.

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