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ガス相と溶液中の反応性とメカニズムを直接比較する

John M Garver1, Yao-ren Fang, Nicole Eyet

  • 1Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309, USA.

Journal of the American Chemical Society
|March 2, 2010
PubMed
まとめ

シアン酸イオンのガス相と溶液の反応をアルキルイオダイドと比較すると,過渡状態に対する溶媒効果が明らかになる. 溶解ルールは溶液の振る舞いを予測しますが,静電力によるガス相反応では失敗します.

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