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Updated: Jun 15, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
08:51

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core

Published on: October 24, 2017

ダイベンゾチオフェンS酸化物誘導体の光解酸素化は,水中介質で行われます

James Korang1, Whitney R Grither, Ryan D McCulla

  • 1Department of Chemistry, Saint Louis University, 3501 Laclede Avenue, Saint Louis, Missouri 63103, USA.

Journal of the American Chemical Society
|March 9, 2010
PubMed
まとめ

研究者たちは,強力な酸化物質である水中の原子酸素 (O ((((3) P)) を生成するための簡単な方法を開発しました. 水中の特定の硫酸化物の光分解は,pHに依存するメカニズムを通じて,高量子率で原子酸素を生成します.

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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst09:12

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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