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関連する概念動画

Alkyl Halides02:45

Alkyl Halides

Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Electrophiles02:28

Electrophiles

This lesson explains the definition, classification, and characteristic features of an electrophile that are key features of nucleophilic substitution reactions. An analysis of their charge and orbital picture helps understand their reactivity for seeking electrons. Electrophiles can be classified into positive and neutral species. Other classes include free radicals and polar functional groups.
While a positive electrophile, like a proton, reacts due to its vacant, low-energy 1s orbital, the...
Ions as Acids and Bases02:54

Ions as Acids and Bases

Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Mass Spectrometry: Alkyl Halide Fragmentation01:22

Mass Spectrometry: Alkyl Halide Fragmentation

Chlorine isotopes exist as 35Cl and 37Cl in a 3:1 ratio, while bromine isotopes exist as 79Br and 81Br in a 1:1 ratio. The mass spectrum of alkyl halides typically produces two distinct molecular ion peaks, the molecular ion peak, [M], and the molecular ion plus two, [M + 2] peak. The relative heights of these two peaks are proportional to the isotopic abundance ratios of the halide. For example, 2‐chloropropane and 1‐bromopropane display two peaks with relative peak heights in a 3:1 and 1:1...
Halogens03:01

Halogens

Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group.

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関連する実験動画

Updated: Jun 15, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

ディアルキルクロロニウムイオン

Evgenii S Stoyanov1, Irina V Stoyanova, Fook S Tham

  • 1Department of Chemistry, University of California, Riverside, California 92521-0403, USA. evgeniis@ucr.edu

Journal of the American Chemical Society
|March 12, 2010
PubMed
まとめ

カーボラン酸は,クロロアルカンと反応して,安定したダイアルキルクロロニウム塩を形成する. これらの塩は,化学合成に有用な強力な電性メチル化剤へのクリーンな合成経路を提供します.

科学分野:

  • 無機化学 無機化学とは
  • 有機化学 オーガニック・ケミストリー
  • 超分子化学 超分子化学

背景:

  • カーボラン酸は,独特の性質を持つ強い酸です.
  • ダイアルキルクロロニウムイオンは,反応性中間物質である.

研究 の 目的:

  • 新しいダイアルキルクロロニウムイオン塩を合成し,特徴づけること.
  • 安定性と反応性を調べるため.
  • 新しいメチル化剤を開発するために.

主な方法:

  • カルボラン酸H ((CHB ((11) Cl ((11)) とクロロアルカンとの反応.
  • 構造的決定のためのX線結晶学.
  • 振動分析のための赤外線 (IR) スペクトロスコピー.

主要な成果:

  • 隔離可能なダイアルキルクロロニウムイオン塩 [R(2)Cl][CHB(11)Cl(11) ]を合成し,室温で安定していることが判明しました.
  • X線構造は,曲ったカチオン幾何学 (C-Cl-C角101.5-105.8°) を明らかにした.
  • ディメチルクロロニウム塩を加熱すると,サブライマブルなメチル化剤 CH(3)(CHB(11)Cl(11)) が得られました.

さらに関連する動画

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

関連する実験動画

Last Updated: Jun 15, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

結論:

  • カルボラン酸から派生したダイアルキルクロロニウム塩は安定しており,構造的に特徴付けられています.
  • 新しい強力な電性メチル化剤が開発されました.
  • この研究は,合成におけるカルボラン化学の有用性を拡大する.