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Updated: Jun 15, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

シリリウム触媒を用いたアリファティックな炭素-ハロゲン結合の水素デハロゲン化およびその他の水素デハロゲン化

Christos Douvris1, C M Nagaraja, Chun-Hsing Chen

  • 1Department of Chemistry, Brandeis University, 415 South Street, Waltham, Massachusetts 02454, USA.

Journal of the American Chemical Society
|March 12, 2010
PubMed
まとめ

新しい触媒は,C-F,C-Cl,C-Br結合の効率的な水分除を,トライアキルシランを用いて可能にします. この反応は,選択的にC ((sp ((3)) -ハロゲン結合を標的とし,CF ((4) を除き,広範囲の基板範囲を提供します.

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