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Updated: Mar 23, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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ハイパーバレント系ジメルの金属化:分子とバンドの視点

John S Tse1, Alicea A Leitch, Xueyang Yu

  • 1Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2, Canada.

Journal of the American Chemical Society
|March 13, 2010
PubMed
まとめ

ビスティアセレナゾリルラジカルジメルは,高圧 (5-9 GPa) 下で弱金属状態を示す. この金属化は,分子内構造の変化と分子間相互作用によって引き起こされ,HOMO-LUMOギャップの崩壊とバンドギャップの閉塞につながります.

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