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Updated: Jun 14, 2026

Concurrent Quantitative Conductivity and Mechanical Properties Measurements of Organic Photovoltaic Materials using AFM
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高移動性半導体ナフトジチオフェン共ポリマーである.

Itaru Osaka1, Toru Abe, Shoji Shinamura

  • 1Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8527, Japan. iosaka@hiroshima-u.ac.jp

Journal of the American Chemical Society
|March 20, 2010
PubMed
まとめ

ナフト[1,2-b:5,6-b']ディチオフェン (NDT) を含む新型半導体ポリマーは,高電荷キャリアの移動性を示す. これらの材料は,秩序ある構造のため,印刷可能な電子機器の有望性を示しています.

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...