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Updated: Jun 14, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

N-スルフォニルイミンと半安定したトリフェニルフォスフォニウムイリドの高度に調節可能なステレオ選択的オレフィネーションです

De-Jun Dong1, Hai-Hua Li, Shi-Kai Tian

  • 1Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.

Journal of the American Chemical Society
|March 23, 2010
PubMed
まとめ

この研究では,アルデヒドの代わりにN-スルフォニルイミンを用いた新しいウィティグ反応プロトコルが導入されています. この方法はアルケンの合成におけるステレオ選択性を大幅に高め,Z-およびE-アルケンの同位体に対して99:1以上の選択性を達成します.

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