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Updated: Jun 14, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Published on: June 24, 2022

プラチナ触媒による分子内水素酸化:アルケンのPt-N結合への挿入の証拠

Jessica M Hoover1, Antonio Dipasquale, James M Mayer

  • 1Department of Chemistry, University of Washington, Campus Box 351700, Seattle, Washington 98195-1700, USA.

Journal of the American Chemical Society
|March 26, 2010
PubMed
まとめ

ディカチオンプラチナ (II) 複合体はアルケンの水素酸化を触媒化し,効率的にN-アミノラクトームを形成する. この発見は,価値あるヘテロサイクリック化合物の新しい合成経路を提供します.

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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