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Updated: Jun 14, 2026

Synthesis of In37P20(O2CR)51 Clusters and Their Conversion to InP Quantum Dots
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Synthesis of In37P20(O2CR)51 Clusters and Their Conversion to InP Quantum Dots

Published on: May 7, 2019

トリアリルフォスフィンインジウムトリハリドアドクトの固体115Inと31PのNMR研究

Fu Chen1, Guibin Ma, Guy M Bernard

  • 1Department of Chemistry, Gunning/Lemieux Chemistry Centre, University of Alberta, Edmonton, Alberta, Canada T6G 2G2.

Journal of the American Chemical Society
|March 31, 2010
PubMed
まとめ

本研究では,NMRスペクトロスコピーとDFT計算を用いたトリアリルフォスフィンインジウム (III) トライハリドアダクトを調査しています. インジウムのシールドはハロゲン型によって変化し,スピン・スピン結合は,フォスフィンリガンドの基本性に左右されます.

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
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