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Updated: Jun 13, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

エチルベンゼンデヒドロゲナーゼ反応機構のAb initioモデリング

Maciej Szaleniec1, Tomasz Borowski, Karola Schühle

  • 1Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239 Krakow, Poland. ncszalen@cyf-kr.edu.pl

Journal of the American Chemical Society
|April 15, 2010
PubMed
まとめ

エチルベンゼン脱水酸化酵素 (EBDH) は,エチルベンゼンの酸化を,2つの1電子転送メカニズムを通じて触媒化し,中間基と重要なヒスティジン残基を含む. 動的同位体効果は,pHに依存する速度決定のステップと潜在的な陽子トンネリングを明らかにします.

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