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Updated: Jun 13, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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銅で触媒化されたウルマン型反応のメカニズムとリガンド誘導的選択性の計算による探求

Gavin O Jones1, Peng Liu, K N Houk

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|April 15, 2010
PubMed
まとめ

計算による研究は,リンガンドの選択が,銅で触媒化されたウルマン型結合反応の選択性を決定することを明らかにしています. 特定のリガンドは,主にアリルハリドの活性化段階において,N-またはO-アリレーションが起こるか否かを影響する.

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