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Updated: Jun 13, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
10:52

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

Jahn-Teller-アクティブ [HIPTN(3) N]MoL複合体の実験的および理論的EPR研究 (L = N(2),CO,NH(3))

Rebecca L McNaughton1, Michael Roemelt, Jia Min Chin

  • 1Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.

Journal of the American Chemical Society
|May 1, 2010
PubMed
まとめ

Jahn-Teller歪みを持つ三角対称モリブデン化合物が研究されました. 多参照波動関数アプローチは,モリブデンイオンによる窒素固定に関する洞察を明らかにした.

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Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals

Ideally, an unpaired electron shows a single peak in the EPR spectrum due to the transition between the two spin energy states. However, coupling interactions can occur between the spins of the unpaired electron and any neighboring spin-active nuclei. This hyperfine coupling results in hyperfine splitting, where the EPR signal is split into multiplets. The signals split into 2nI + 1 peaks, where n is the number of equivalent nuclei and I is the nuclear spin. These splitting patterns provide...
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Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

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