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Updated: Jun 12, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

ニトリルのルテニウム触媒化水素化:メカニズムに関する洞察

Rebeca Reguillo1, Mary Grellier, Nicolas Vautravers

  • 1Laboratoire de Chimie de Coordination, CNRS, UPS, INPT, Université de Toulouse, 205 Route de Narbonne, F-31077 Toulouse, France.

Journal of the American Chemical Society
|May 21, 2010
PubMed
まとめ

ルテニウム触媒は,ベンゾニトリルからベンジラミンへの軽度の水素化を可能にします. この研究は,触媒サイクルにおける主要な中間物質を特定し,N-調整またはイミン形成を経由して早期のベンゾニトリル活性化,C-H活性化が続くことを明らかにします.

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