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Updated: Jun 12, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

ペプチド触媒による非対称ブロミネーションによるビアリルアトロピソメアのダイナミック・キネティック解像度

Jeffrey L Gustafson1, Daniel Lim, Scott J Miller

  • 1Department of Chemistry, Yale University, 225 Prospect Street, Post Office Box 208107, New Haven, CT 06520-8107, USA.

Science (New York, N.Y.)
|June 5, 2010
PubMed
まとめ

この研究は,バイアリル化合物の動的運動解像度のための新しいトリペプチド触媒を導入しています. この方法は,高いエナチオセレクティブ性を持つアトロピソメリックビアリルリガンドの効率的な非対称合成を可能にします.

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Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation

Introduction
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Regioselectivity and Stereochemistry of Hydroboration

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