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Updated: Jun 12, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

サイクロプロペノンケタルの分子内 [1 + 2] と [3 + 2] のサイクル添加反応

Paresma R Patel1, Dale L Boger

  • 1Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Journal of the American Chemical Society
|June 10, 2010
PubMed
まとめ

この研究では,サイクロプロペノンケタルの最初の分子内熱反応が報告されています. これらの反応は,穏やかな条件下で [3 + 2] サイクルロードダクトを生み出し,新しい合成経路を提供します.

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