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Updated: Jun 12, 2026

Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase
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C-SとC-Nの二重結合を持つギルマン反応剤の複合体:シグマまたはパイ結合?

Steven H Bertz1, Yasamin Moazami, Michael D Murphy

  • 1Department of Chemistry, University of North Carolina-Charlotte, Charlotte, North Carolina 28223, USA. sbertz1@uncc.edu

Journal of the American Chemical Society
|June 15, 2010
PubMed
まとめ

ギルマン反応剤のような有機銅反応剤は,チオカルボニル化合物と反応して新しい銅複合体を形成します. NMRで研究されたこれらの反応は,Cu (III) 酸化状態の銅を示唆し,C-N二重結合複合体を産生する.

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