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Updated: Jun 11, 2026

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
10:17

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

Published on: February 7, 2019

Rh (I) -触媒 (5 + 2) サイクル添加における地域選択性の電子およびステリック制御:実験と理論

Peng Liu1, Lauren E Sirois, Paul Ha-Yeon Cheong

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA.

Journal of the American Chemical Society
|July 1, 2010
PubMed
まとめ

ヴィニルcyclopropanes (VCPs) とalkynesの間のRh(I) -触媒 (5 + 2) サイクル添加は,置換物位置に基づいて予測可能な地域選択性を示しています. 移行状態におけるステリック効果と電子効果は,これらの重要な有機反応の結果を支配する.

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Solid-phase Synthesis of [4.4] Spirocyclic Oximes

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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

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