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Updated: Jun 10, 2026

Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source
06:26

Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source

Published on: August 17, 2018

炭素一酸化物によって誘発された二酸化窒素とグループ4メタロセンの分裂:N-H結合形成とCO脱酸素化への反応範囲と結合

Donald J Knobloch1, Emil Lobkovsky, Paul J Chirik

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.

Journal of the American Chemical Society
|July 29, 2010
PubMed
まとめ

炭素一酸化物 (CO) は,ジルコノセンとハフノセンの複合体における二酸化窒素 (N2) の分裂を誘導し,オキシミドリガンドを形成する. ハフニウム複合体は,ジルコニウムよりもクリーンなN2分裂を示し,さらなる反応により,イソシアナート複合体を産生します.

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