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Updated: Jun 10, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

アリルハリドと原発アルコールのパラジウム触媒C-O結合反応の一般的で効率的な触媒である

Saravanan Gowrisankar1, Alexey G Sergeev, Pazhamalai Anbarasan

  • 1Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

Journal of the American Chemical Society
|August 3, 2010
PubMed
まとめ

新しいパラジウム触媒結合法では,新しいフォスフィンリガンドを使用して,アリルハリドとプライマリアルコールからアルキルアリルエーテルを効率的に合成します. この方法は,競合するアルコールタイプでも,高い収穫量と地域選択性を示しています.

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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

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Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation

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One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Conversion of Alcohols to Alkyl Halides

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction

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Vicinal Diols via Reductive Coupling of Aldehydes or Ketones: Pinacol Coupling Overview

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