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Updated: Jun 10, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

Pd触媒によるエナチオセレクティブアルリル-アルリルクロスカップリング

Ping Zhang1, Laura A Brozek, James P Morken

  • 1Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA.

Journal of the American Chemical Society
|August 5, 2010
PubMed
まとめ

この研究では,アリル炭酸塩とアリルボロン酸塩の間で,パラジウム触媒によるクロスカップリング反応を詳細に説明しています. リンガンドの噛み角は地域選択性を制御し,枝分かれした製品を好み,キラルリンガンドは,アリル置換製品のエナチオ選択的合成を可能にします.

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