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Updated: Jun 9, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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ニトリルの振動的なシフトの分解は,静電効果と水素結合効果に変換される

Aaron T Fafarman1, Paul A Sigala, Daniel Herschlag

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.

Journal of the American Chemical Society
|September 3, 2010
PubMed
まとめ

この研究は,赤外線 (IR) スペクトロスコピーと核磁共振 (NMR) 化学シフトを使用してタンパク質内の静電場を正確に測定するための新しい方法を導入しています. この技術は化学相互作用を修正し,複雑な生物環境でも正確な分析を可能にします.

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