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Updated: Jun 9, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

核性スカンジウムカルベンの複合体

Marie Fustier1, Xavier F Le Goff, Pascal Le Floch

  • 1Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653 (DCPH), Département de Chimie, Ecole Polytechnique, 91128 Palaiseau Cedex, France.

Journal of the American Chemical Society
|September 4, 2010
PubMed
まとめ

研究者らは,ゲミナルダイアニオン前駆体を使って,新しいスカンジウムカルベンの複合体を合成した. この複合体は核性カルベンの振る舞いを示し,ユニークなスカンディア-ウィッティッグ反応を促進し,アルケンの誘導体と希少なオクソ-スカンジウム種を形成します.

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