チエニレンビニレン分子ワイヤの自己組み立てにより,金属伝導性がドーピングされた半導体ゲルに成る
Seelam Prasanthkumar1, Anesh Gopal, Ayyappanpillai Ajayaghosh
1Photosciences and Photonics Group, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology, CSIR, Trivandrum 695019, India.
Journal of the American Chemical Society
|September 4, 2010
まとめ
オリゴ・チエニレン・ビニレン (OTV) ベースの新型ジェラターは,高伝導性を示しています. OTV2は金属伝導率4.8S/cmを証明しており,これはオルガンゲレーターの最高値であり,有機電子工学にとって有望である.
科学分野:
- マテリアルサイエンス 材料科学
- オーガニック・エレクトロニクス
背景:
- オリゴ ((チエニレン・ビニレン) (OTV) 誘導体は,高度な材料の応用のために調査されています.
- 高い電気伝導性を有するオルガンゲレーターの開発は,有機電子工学にとって極めて重要です.
研究 の 目的:
- 新しいOTVベースのジェラターを合成し,特徴づけること.
- これらの新しい材料の伝導性および凝縮性特性を調査する.
主な方法:
- 異なる結合長さのOTV1とOTV2の合成.
- 凝縮剤の強さを評価するための凝縮剤試験.
- ドーピング後の電気伝導度測定.
主要な成果:
- 結合時間が長いOTV2は,OTV1.1と比較してより強いゲルを形成します.
- 4.8 S/cmの金属伝導率を達成しました.
- 大量ヘテロ結合装置での使用の可能性が実証されています.
結論:
- OTVベースのジェラターは,有機電子機器に適した高伝導性を提供します.
- 結合長さの増加はゲルの強度と伝導性を高めます.
- これらの材料は,有機フォトニクスと電子学のアプリケーションに有望です.
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