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Updated: Jun 8, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

ニッケルによって触媒化されたイソシアネートとアレンのエナチオセレクティブ [2 + 2 + 2]サイクロアディション反応

Tomoya Miura1, Masao Morimoto, Masahiro Murakami

  • 1Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|September 16, 2010
PubMed
まとめ

この研究では,イソシアネートおよびアレンからキラル二酸化ピリミジン-2,4-ダイオンを合成するためのニッケル触媒化されたサイクル添加反応を導入しています. この方法は,エナティオメリックに濃縮された化合物を効率的に生成します.

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Cycloaddition Reactions: Overview

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[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction

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Cycloaddition Reactions: MO Requirements for Thermal Activation

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