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Updated: Jun 8, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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N-ヘテロサイクルのカルベン-ディジリン複合体とそのZnCl2に対する反応性

Torahiko Yamaguchi1, Akira Sekiguchi, Matthias Driess

  • 1Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.

Journal of the American Chemical Society
|September 17, 2010
PubMed
まとめ

研究者は,N-ヘテロサイクリックカルベン (NHC) を含むディジリン複合体を合成した. 亜鉛塩化物との複合は,シリコン-シリコンの二重結合の幾何学的変化を誘導し,トランスからシスへと変化させた.

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