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Coordination Number and Geometry02:57

Coordination Number and Geometry

For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
Lattice Centering and Coordination Number02:33

Lattice Centering and Coordination Number

The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Adaptability of Cytoskeletal Filaments01:12

Adaptability of Cytoskeletal Filaments

The cytoskeleton is a complex dynamic structure performing varied functions based on cellular requirements. The adaptability of the individual filaments in the cytoskeleton determines their ability to perform various functions within the cell. It can undergo rapid reorganization during processes like cell division or remain stable for several hours as in the interphase. The adaptability of these filaments depends on stringent regulatory mechanisms. The microfilament and microtubules of the...
Clathrin Coated Vesicles01:12

Clathrin Coated Vesicles

Clathrin-coated vesicles use endocytosis to transport receptors and lysosomal hydrolases from the Golgi to the lysosome in the late secretory pathway. Clathrin-mediated endocytosis was the first described endocytic process, and Clathrin-coated vesicles remain one of the most well-studied transport vesicles. The molecular machinery that generates clathrin-coated vesicles comprises over 50 proteins that precisely coordinate vesicle formation. Cell surface receptors concentrated in indented sites...
Protein Complexes with Interchangeable Parts01:57

Protein Complexes with Interchangeable Parts

Groups of proteins may form a complex where each protein in this complex has a different role in the overall execution of the complex’s function. Often some of the proteins in the complex can be replaced by a closely related variant to give a complex that contains many of the same components yet is functionally distinct.
The SCF ubiquitin ligase is a protein complex of five individual proteins. This complex attaches ubiquitin to other target proteins to mark them for degradation. In order to...
Masonry Cavity Walls01:26

Masonry Cavity Walls

Cavity walls feature a hollow space between the outer and inner wythes, connected only by corrosion-resistant metal ties. When water seeps through the outer wythe, it descends within this cavity, intercepted by flashing and eventually exiting through weep holes. To enhance moisture resistance, the inner wythe's cavity side often receives damp-proofing, doubling as an air barrier. The cavity can also house insulation to mitigate heat transfer.
Maintaining a clean cavity during construction is...

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関連する実験動画

Updated: Jun 8, 2026

A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage
04:49

A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage

Published on: June 6, 2025

調整ケージは,可変の穴のサイズを持つ調整ケージです.

Sebastian Mirtschin1, Adam Slabon-Turski, Rosario Scopelliti

  • 1Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|September 24, 2010
PubMed
まとめ

新しい六核調整ケージは大きく膨張し,大きな穴を作り出します. この膨張により,2つのコロネン分子が構造内にうまく封じ込めることができます.

科学分野:

  • 超分子化学 超分子化学
  • 協調化化学について
  • マテリアルサイエンス 材料科学

背景:

  • 調整ケージは,調節可能な性質を持つ超分子構造である.
  • 穴の大きさを制御することは,分子封じ込めアプリケーションにとって非常に重要です.

研究 の 目的:

  • 動的空洞を持つ六核調整ケージを開発する.
  • ポリサイクル芳香炭化水素をカプセル化するケージの能力を調査する.

主な方法:

  • 六核の金属有機構造体の合成.
  • 構造の変化を研究するために,可変温度X線 difraktion.
  • ガス吸附と脱吸収は,空洞の体積を決定するアイソテルムである.
  • ゲスト分子のカプセル化を確認するための結晶学.

主要な成果:

  • 六核調整ケージは,空洞の体積がほぼゼロから500 Å以上まで大きく変化している (3).
  • このケージは,拡大した穴の中に2つのコロネン分子を成功裏に封じ込めました.
  • 構造分析により,封装されたコロネン分子の存在と方向性が確認されました.

結論:

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The Double-H Maze: A Robust Behavioral Test for Learning and Memory in Rodents

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Last Updated: Jun 8, 2026

A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage
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A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage

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Preparation and Maintenance of Bioexclusion IsoPositive Cage Experiment for Human Fecal Transplantation into Germ-Free Mice
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Preparation and Maintenance of Bioexclusion IsoPositive Cage Experiment for Human Fecal Transplantation into Germ-Free Mice

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The Double-H Maze: A Robust Behavioral Test for Learning and Memory in Rodents
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The Double-H Maze: A Robust Behavioral Test for Learning and Memory in Rodents

Published on: July 8, 2015

  • 開発された調整ケージは,驚くべきダイナミックな穴の膨張を示しています.
  • このダイナミックな振る舞いは,コロネンなどの大きなゲスト分子のサイズ選択的封じ込みを可能にします.
  • この発見は,適応可能な超分子構造を用いたホスト・ゲスト化学と分子認識の新たな道を開く.