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Updated: Jun 7, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
05:51

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

原子トンネリングに対する電子効果:モノメリックパラ置換ベンゾ酸誘導体の構成性イソメリゼーション

Shadi Amiri1, Hans Peter Reisenauer, Peter R Schreiner

  • 1Institute for Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany.

Journal of the American Chemical Society
|October 23, 2010
PubMed
まとめ

ベンゾ酸の不安定なEコンフォマーをデュテリウムラベルを用いて特定し,トンネリングによるZ形への急速な変換を観察しました. このトンネリングプロセスに対する置換効果は定量化され,原子トンネリングのための最初のハメット関係が確立されました.

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