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Updated: Jun 7, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
05:51

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

ハイドリド-プロトン伝達 (HPT) 理論 カーボニル還元 [Os(III) ((tpy) ((Cl) ((NHCHCH ((3))) ((NSAr)) ]による

Daniel H Ess1, Cynthia K Schauer, Thomas J Meyer

  • 1Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States.

Journal of the American Chemical Society
|October 29, 2010
PubMed
まとめ

この研究は,新しいオスミウム複合体が,ヒドリド-陽子移転によるカルボニル還元を促進することを示しています. 水またはアルコールは,この量子力学分析において,陽子伝送機構の活性化に不可欠である.

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Carboxylic Acids to Primary Alcohols: Hydride Reduction01:17

Carboxylic Acids to Primary Alcohols: Hydride Reduction

Carboxylic acids, upon reaction with strong reducing agents such as lithium aluminum hydride followed by hydrolysis, undergo reduction to form primary alcohols.
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Acid Halides to Alcohols: LiAlH4 Reduction

Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
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Esters to Alcohols: Hydride Reductions

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