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Updated: Jun 7, 2026

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
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挿入ポリメリゼーションにおけるメタクリラートの反応性

Thomas Rünzi1, Damien Guironnet, Inigo Göttker-Schnetmann

  • 1Chemical Materials Science, Department of Chemistry, University of Konstanz, 78464 Konstanz, Germany.

Journal of the American Chemical Society
|November 4, 2010
PubMed
まとめ

この研究では,パラジウム触媒がエチレンをポリエチレンにポリメリゼーションし,メチルメタクリlate (MMA) が存在する場合でも,メチルメタクリlate (MMA) を除外することを示しています. この選択性は,モノマー挿入における熱力学的差異によるものであり,機能化されたポリマーを可能にします.

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