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Updated: Jun 6, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
10:52

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Published on: July 27, 2022

CpCr[(ArNCMe) 2CH](R) 複合体によるクロム (((III) -アルキル結合の同解を探求する

K Cory MacLeod1, Julia L Conway, Brian O Patrick

  • 1Department of Chemistry, University of British Columbia Okanagan, 3333 University Way, Kelowna, BC, Canada V1V 1V7.

Journal of the American Chemical Society
|November 13, 2010
PubMed
まとめ

研究者は,R群がクロミウム-R結合同解をどのように影響するかを研究するために,パラマグネティッククロミウム (III) モノヒドロカルビル複合体を合成した. R群のステリックおよび電子的要因は結合強度と反応性に影響を与え,いくつかの複合体はホモリシスを経験し,他の複合体は光分解によって反応します.

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