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Updated: Jun 6, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

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バイオインスピレーションの鉄触媒を用いたオレフィンシスジヒドロキシル化. Fe (II) /Fe (IV) 触媒サイクルに関する証拠

Paul D Oldenburg1, Yan Feng, Iweta Pryjomska-Ray

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, United States.

Journal of the American Chemical Society
|November 26, 2010
PubMed
まとめ

鉄 (((II) 複合体とN-酸化ディピリジン-2-イルメチラミン (R-DPAH) リガンドは,過酸化水素を使用してオレフィンシス-二酸化水素を触媒化する. これは Rieske ダイオキシゲナスを模倣し,効率的な cis-diol 形成のための Fe (II) / Fe (IV) レドックスサイクルを示唆します.

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