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Updated: Jun 6, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

ルテニウムN-ヘテロサイクリックカルベンの複合体におけるC-N結合活性化の実験的および計算的調査

L Jonas L Häller1, Michael J Page, Stefan Erhardt

  • 1School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, United Kingdom.

Journal of the American Chemical Society
|December 7, 2010
PubMed
まとめ

この研究では,ルテニウムN-アルキル置換ヘテロサイクリックカルベン (NHC) 複合体の前C-H活性化により,不可逆的なC-N結合活性化が可能であることが明らかになりました. NHCリガンドの置換剤の改変は,活性化バリアと反応経路に大きな影響を及ぼします.

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