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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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ポルフィリンが4つのアントラセネスと融合した

Nicola K S Davis1, Amber L Thompson, Harry L Anderson

  • 1Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.

Journal of the American Chemical Society
|December 15, 2010
PubMed
まとめ

研究者らは,新しい溶融テトラアントラセニルポルフィリンを合成した. この新しいポルフィリン誘導体は,強烈な近赤外線吸収と小さなエネルギーギャップを含むユニークな光学および電子特性を示しており,先進的な材料のアプリケーションに有望です.

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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