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Updated: Jun 5, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

ビスカルベンのRh (I) 複合体による水酸化:シリレンベースのメカニズムの実験的証拠

Peter Gigler1, Bettina Bechlars, Wolfgang A Herrmann

  • 1WACKER-Institut für Siliciumchemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching b. München, Germany.

Journal of the American Chemical Society
|December 29, 2010
PubMed
まとめ

この研究では,N-ヘテロサイクルビスカルベンロジウム ((I) 複合体を用いた水溶化のメカニズムが詳細に示され,提案された触媒サイクルが確認され,副産物形成が説明されています. ディヒドロシランとの水酸化と脱水結合反応は,共通のメカニズム経路を共有しています.

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Regioselectivity and Stereochemistry of Hydroboration

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