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Updated: Jun 4, 2026

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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メトキシラジカルのイソメリゼーション:酸性触媒による分子内水素原子移転を媒介する

Robert J Buszek1, Amitabha Sinha, Joseph S Francisco

  • 1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084, United States.

Journal of the American Chemical Society
|February 1, 2011
PubMed
まとめ

酸性触媒は,CH(3) OのCH(2) OHへの基質イソメリゼーションの活性化エネルギーを大幅に低下させます. 硫酸の触媒は反応速度を12倍以上高め,禁止されたガス相の急性反応を可能にします.

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