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Updated: Jun 4, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

O2を持つPd(I) -Pd(I) ダイマーの反応性:平衡状態のモノハプトPd超酸化物と二パラジウム過酸化物の反応性

Rafael Huacuja1, Daniel J Graham, Claudia M Fafard

  • 1Department of Chemistry, Texas A&M University, College Station, Texas 77842, United States.

Journal of the American Chemical Society
|March 1, 2011
PubMed
まとめ

光で活性化されたパラジウムジメルは,酸素と反応して,パラジウム-超酸化物またはパラジウム-過酸化物複合体を形成します. これらの正方形平面パラジウム (II) 複合体は,酸素と均衡状態にあり,電子密度は超酸化物リガンドに局限しています.

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